An experimental investigation of the effects of thawed soil depth on rill flow velocity

Water flow velocity is an important hydraulic variable in hydrological and soil erosion models, and is greatly affected by freezing and thawing of the surface soil layer in cold high-altitude regions. The accurate measurement of rill flow velocity when impacted by the thawing process is critical to simulate runoff and sediment transport processes. In this study, an electrolyte tracer modelling method was used to measure rill flow velocity along a meadow soil slope at different thaw depths under simulated rainfall. Rill flow velocity was measured using four thawed soil depths (0, 1, 2 and 10 cm), four slope gradients (5°, 10°, 15° and 20°) and four rainfall intensities (30, 60, 90 and 120 mm·h⁻¹). The results showed that the increase in thawed soil depth caused a decrease in rill flow velocity, whereby the rate of this decrease was also diminishing. Whilst the rill flow velocity was positively correlated with slope gradient and rainfall intensity, the response of rill flow velocity to these influencing factors varied with thawed soil depth. The mechanism by which thawed soil depth influenced rill flow velocity was attributed to the consumption of runoff energy, slope surface roughness, and the headcut effect. Rill flow velocity was modelled by thawed soil depth, slope gradient and rainfall intensity using an empirical function. This function predicted values that were in good agreement with the measured data. These results provide the foundation for a better understanding of the effect of thawed soil depth on slope hydrology, erosion and the parameterization scheme for hydrological and soil erosion models.     

薄分子云湍流结构函数的倾角改正及其应用

通过结构函数可以测量湍流的能量级联速率.在实际观测中,无法测量分子云中气体的3维速度,这使得其湍流结构函数难以测量.对垂直于视线方向的薄分子云的情形,结构函数Stt2可以通过云核速度弥散(core velocity dispersion,CVD)进行测量,CVD2=1/2Stt2.对此进行推广,对于不垂直于视线方向的薄分子云,CVD2=1/2Stt2(1-1/8cos2θ)R2/3,其中,θ是视线方向与投影方向的夹角,平均投影距离与3维距离之比R可以用第2类椭圆积分E(k,φ)表示为R=2/πE(cosθ,π/2).     

基于波形特征的露天钼矿微震事件的识别分析——以卓资山钼矿为例

基于前人研究成果以及现场的实测结果，采用卓资山露天钼矿微震监测项目产出资料，提取了5类微震事件的波形特征和时频特征。波形特征显示:微地震的振幅、辐射均匀性和频率变化特征表明微地震是由于岩层受到单力偶和剪切力作用破裂而产生；爆破具有P波初动方向向上、S波不易识别的特点，包含“初震段、主震段、尾波段”三段变化形态；小型边坡滑坡波事件属楔体滑坡，是由多个“加速—缓冲—终止”构成，波形是由包络线呈“V”字形的多组脉冲波列组成；机械开采震动事件具有自振能量不变、脉冲幅度相差很大、持续时间间隔不确定的特点；运输车辆波形振幅具有形态“弱—强—弱”、等频率、包络线呈多段纺锤形的特征。时频空间分布可以分为相对独立、界限分明的两类:一类包含微地震、爆破、机械开采、小型边坡滑坡事件，另一类只包含车辆运输事件。     

国外OTA与传统旅游企业竞合关系研究综述

作为重要的在线营销渠道，OTA一直是传统旅游企业的重要合作伙伴之一。无论是OTA抢夺资源还是传统旅游企业对抗升级，双方之间的竞争趋势愈加明显。由此，相关方面的研究逐步增多。国外研究从OTA与饭店、航空公司等传统旅游企业合作、竞争和竞合平衡三个方面入手，主要围绕OTA与饭店的竞合问题展开。重视实证分析，采用数理统计和模型构建等定量研究方法，针对航空公司和饭店企业，从市场细分、定价、客房分配等角度提出实现双方竞合平衡的方案。建议今后加强对OTA和传统旅游企业合作模式变化的跟踪分析，关注OTA与景区、餐馆等旅游供应商的博弈关系。     

Hydrologic separation and their contributions to N loss in an agricultural catchment in hilly red soil region

The impacts of hydrological processes on N loss is of great value to understand the N transport at catchment scale,which is far from clear. Rainfall, soil water, groundwater and stream water and their N concentrations were monitored from March 2017 to February 2018 in Sunjia agricultural catchment of the red soil critical zone. Objectives of this study were:(1) to determine the dynamics of N concentration of different waters and their N loads;(2) to assess their contributions to N load of streamflow in the paddy and upland mixed agricultural catchment. Our results showed that the N concentrations of soil water(4.8 mg L~(-1)) and groundwater(6.0 mg L~(-1)) were the highest, approximately 2 to 5 times higher than those of stream water(2.7 mg L~(-1)), rain water(1.7 mg L~(-1)) and irrigation water(1.2 mg L~(-1)). The N net loss of the catchment(38.2 kg ha~(-1) yr~(-1))accounted for 15% of the total fertilizer N input. Rainy season(April–June) was a high-risk period of N loss, contributing to more than one third of the total annual loss amount. Using end-member mixing analysis model(EMMA), we found groundwater(whose discharge accounted for 25% of the catchment streamflow) was an important source for the N loss in the agricultural catchment. Even in this catchment with coexisting upland and paddy field ecosystems, identified end-members could be used to predict the N load well(R~20.87, p0.001). These results can deepen our understanding of the relationship between hydrological process and N transport in the red soil critical zone and are also helpful to improve the water and fertilizer management in subtropical agricultural catchment.     

Temporal-Spatial Variation of Surface Suspended Matter and Controlling Factors in the Inner Shelf of the East China Sea in Winter

Based on the observed surface suspended matter in the East China Sea in February 2007 and June 2015, an empirical model was established using L1 b's band 4 data to retrieve surface suspended matter from the Moderate Resolution Imagine Spectroradiometer Terra imagery. The squared correlation coefficient is 0.8358, and the root mean square error is 0.4285 mg L-1. The model reflects the distribution characteristics of surface suspended matter in the inner shelf of the East China Sea. In this paper, the satellite images of the study area were retrieved in January from 2001 to 2015, and the monthly distribution of surface suspended matter were obtained. The inter-annual distribution of the study area is similar, and the concentration of surface suspended matter is higher near the shore than offshore. A large amount of surface suspended matter is transported southeast under the influence of Zhejiang and Fujian coastal current and Taiwan warm current. Only a small amount of surface suspension can reach the Kuroshio area. The surface suspended matter concentration changes obviously near the estuary because of the effect of differences in the flux of the Yangtze River. Meanwhile, winter monsoon, temperature front, El Ni?o events, and other factors affect the distribution of surface suspended matter in 100 m isobath to coastal water but minimally influence the distribution in 100 m isobath to deep sea.     

桂林-阳朔地区DEM地形特征与岩性相关性分析及分类研究

地形地貌是岩性解译的重要信息,地形因子作为描述DEM数字曲面几何特征的定量指标参数,可用来定量化表达不同岩性所在地区地形地貌特征。本文以桂林-阳朔地区为研究区,研究地形因子数学、地质意义,建立岩性与地形因子组合间的定量关联,进而实现岩石类型划分。本文基于ASTERGDEM提取坡度、起伏度等12个地形因子,在分析各个地形因子地质意义基础上,通过聚类分析及方差分析的多元统计分析方法,研究各岩性地形因子特性及其关联性,建立研究区岩性之间的定量差异;此外,利用因子分析方法研究岩性分类过程中的主导因素,确定适宜岩性分类方法以实现定量化岩性分类。实验结果表明：不同岩性、不同地形地貌的地形因子（组合）之间具有显著差异,基于因子分析得到的宏观地形复杂度指数（MTI）以及微观曲率指数（MCI）对岩石类型的分类精度达77.36%。研究表明,地形复杂度等地形因子可用于岩性分类,采用因子分析方法可获取反映地形地貌宏观、微观特征的定量指标,且岩性分类效果良好。     

闽中南平—宁化构造带南华纪陆缘弧岩浆活动：对武夷造山带构造演化的新启示

南平—宁化构造带沿线出露着以万全岩群和楼前组、西溪组等为代表的一系列新元古代火山-沉积岩系。系统的岩石学、年代学和地球化学研究表明,福建明溪和江西瑞金地区的楼前组浅变质英安岩和晶屑凝灰岩分别形成于(729±4)Ma和(735±6.7)Ma(LA-ICP-MS锆石U-Pb法),SiO2含量变化在65.22%～74.54%,相对富Al2O3(11.05%～16.80%)富碱(Na2O+K2O=4.88%～10.19%)而贫CaO、MgO和FeOT,ANK值和A/CNK值分别为1.23～1.78和0.98～1.57,Nb/Ta=12.44～17.28,Nd/Th=2.07～3.51,Ti/Zr=6.08～10.37,Ti/Y=68.51～154.71,属过铝质S型火山岩;明显富集大离子亲石元素(Ba、Rb等)而亏损高场强元素(Nb、Ta、Ti、P等),Zr/Nb=16.65～24.07,Th/Ta=12.94～16.93,δEu呈现明显负异常(0.33～0.62),显示岛弧岩浆岩的地球化学特征。综合区域地质资料及前人研究结果提出,南平—宁化一线在713 Ma前为活动大陆边缘环境,洋壳俯冲引发的岩浆活动形成了沿南平—宁化—瑞金一线展布的陆缘弧中酸性火山岩带,暗示此时南、北武夷之间尚未拼合形成统一的武夷地块,因而华夏地块不存在统一的前南华纪结晶基底。     

全二维气相色谱-电子捕获检测器测定复杂基质土壤中24种有机氯和拟除虫菊酯类农药

目前针对环境样品中有机氯和拟除虫菊酯类农药的检测方法主要有气相色谱法和气相色谱-质谱法（GC-MS），由于气相色谱法采用电子捕获检测器从而具有较高的灵敏度，在污染物的环境行为研究中得到广泛应用，GC-MS法的定性效果好，但检测灵敏度相对偏低。本文研究了2018年土壤详查江苏地区样品中有机氯农药和拟除虫菊酯的残留状况，结果显示，即使经过多次净化仍有20%的样品存在假阳性或基质干扰现象。为了提高定性准确度，同时保证检测灵敏度，实验建立了复杂基质土壤中20种有机氯农药和4种拟除虫菊酯的全二维气相色谱-电子捕获检测器检测方法，最终选择中等极性的TG-35MS为第一色谱柱，非极性的（DB-1）为第二色谱柱，将鲜样与无水硫酸钠混合均匀后，以正己烷-丙酮（1：1，V/V）为提取剂进行索氏提取，采用全二维气相色谱-电子捕获检测器进行检测，外标法定量。各物质的质量浓度均在1.0~500μg/L内与其峰面积呈线性关系，相关系数均大于0.995，检出限为0.02~0.17μg/kg。用标准加入法进行回收实验，测得回收率为80.7%~103.5%，测定值的相对标准偏差（n=6）为1.84%~10.12%。本方法将高灵敏度检测器与全二维色谱相结合，在保证检测灵敏度的同时增加了峰容量，有效去除了基质干扰。相比2018年土壤详查参考方法HJ 835—2017的检出限0.02~0.09mg/kg（全扫模式），本方法检出限显著降低，且操作简单，可为复杂基质样品中的痕量超痕量检测提供参考。     

Spectra of seismic force reduction factors of MDOF systems normalized by two characteristic periods

Seismic force reduction factor(SFRF) spectra of shear-type multi-degree-of-freedom(MDOF) structures are investigated. The modified Clough model, capable of considering the strength-degradation/hardening and stiffnessdegradation, is adopted. The SFRF mean spectra using 102 earthquake records on a typical site soil type(type C) are constructed with the period abscissa being divided into three period ranges to maintain the peak features at the two sitespecific characteristic periods. Based on a large number of results, it is found that the peak value of SFRF spectra may also exist for MDOF, induced by large high-mode contributions to elastic base shear, besides the mentioned two peak values. The variations of the stiffness ratio λk and the strength ratio λF of the top to bottom story are both considered. It is found that the SFRFs for λF≤λk are smaller than those for λF λk. A SFRF modification factor for MDOF systems is proposed with respect to SDOF. It is found that this factor is significantly affected by the story number and ductility. With a specific λF(= λk0.75), SFRF mean spectra are constructed and simple solutions are presented for MDOF systems. For frames satisfying the strong column/weak beam requirement, an approximate treatment in the MDOF shear-beam model is to assign a post-limit stiffness 15%-35% of the initial stiffness to the hysteretic curve. SFRF spectra for MDOF systems with 0.2 and 0.3 times the post-limit stiffness are remarkably larger than those without post-limit stiffness. Thus, the findings that frames with beam hinges have smaller ductility demand are explained through the large post-limit stiffness.